From the Metal Gear Solid series, it's Solid Snake in puzzle form. For use in Pushmo.
Pushmo (or Pullbox for all of you other territories) is a downloadable 3DS title that allows users to solve puzzles by moving blocks outwards and inwards, in addition to creating their own puzzles.
Simply snap a picture of the barcode-like symbol to the right of the puzzle via your 3DS and you're set. Please be aware you must have completed puzzle 109 to be able to scan and play this puzzle. As always, feedback and comments are greatly appreciated.